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Trial operation of the first 10,000-ton CO₂ mineralization demonstration project in the coal chemical industry

2022-06-04View Original

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The first 10,000-ton-scale CO2 mineralization demonstration project in the coal chemical industry began trial operation. Author/Source: Huahua Net Coal Chemicals. Date: 2022-06-03. Clicks: 22. Recently, the Institute of Organic Functional Materials and Application Technologies, in collaboration with Zhongyan Anhui Hongsi Fang Co., Ltd., Tongji University, and Jiangsu Tongcui He Technology Co., Ltd., successfully launched trial operation of China’s first 10,000-ton-scale CO2 mineralization project aimed at producing fully solid-waste-based negative-carbon building materials. This project utilizes bulk solid wastes generated in the coal chemical industry’s production process, such as gasification slag, calcium carbide slag, and fly ash, to undergo a mineralization reaction with the CO2 emissions produced by this industry, without the need for any external heat source or cement. As a result, high-strength building materials with a high carbon sequestration rate and negative carbon emissions are produced, thereby achieving a combination of energy savings, waste utilization, and negative carbon emissions. Achieving \"carbon peak and carbon neutrality\" serves as a powerful driving force and catalyst for industrial structure adjustment. It not only imposes more urgent demands on such adjustment but also offers significant strategic opportunities for the optimization and upgrading of the industrial structure. “The energy resource characteristics of \"abundant coal, limited gas, and scarce oil\" determine that China’s energy structure is dominated by coal. With the goal of \"carbon neutrality\" serving as a strict constraint, efforts are being made to accelerate the low-carbon transformation of traditional industries, to develop a new type of green and low-carbon economy, to promote structural adjustments and upgrades in the industry sector, to reduce energy consumption and carbon emissions in industrial activities, and to gradually achieve decoupling between economic growth and carbon emissions. Industrial carbon emission reduction is of paramount importance in achieving the goals of carbon peak and carbon neutrality. The coal chemical industry is one of the six industries with high energy consumption, and its development faces increasing constraints due to environmental and resource limitations; therefore, it is urgent to seek technological innovations and a low-carbon transformation for this industry. The Institute of Organic Functional Materials and Application Technologies has always focused on technological innovation as its core, striving to become an advocate of low-carbon concepts, a practitioner of low-carbon policies, and a leader in low-carbon development. It implements the \"dual carbon\" strategy in the low-carbon development of enterprises, and actively explores new ideas, technologies, and approaches for the synergistic treatment of large-scale solid waste and carbon dioxide. Following numerous preliminary application studies and thorough preparations, and with the full support of leaders and experts such as Ling Huixun, Chairman and General Manager of Zhongyan Anhui Hong Sifang New Building Materials Technology Co., Ltd., as well as the concerted efforts of all parties involved, the project is now ready for trial production. Cheng Mingzhao, Assistant Director of the Functional Materials Research Institute and Executive Director of the Environmental Protection Center, Dr. Li Chen from the School of Materials Science and Engineering at Tongji University, Ouyang Zhenkui, General Manager of Jiangsu Tongcui He Technology Co., Ltd., along with other relevant officials and professional technicians, were all involved throughout the trial production process of the mineralization line. The trial operation of \"the first domestic coal chemical industry project for the production of full-solid-waste, carbon-negative building materials via CO2 mineralization on a scale of 10,000 tons\" was successfully completed, with excellent results achieved. Verified through pilot-scale production, this project combines advanced technological innovation with engineering feasibility. Industrial solid waste and CO2 gas can undergo mineralization reactions to produce mineralized building materials without the need for any external heat source or cement, and the strength, durability, and other properties of these materials meet current ** and industry standards ; At the same time, it also enables efficient capture and utilization of CO2, with an average carbon sequestration rate of over 15%, truly achieving a combination of energy savings, waste utilization, and carbon reduction. The successful trial operation of this project holds great significance for the low-carbon and sustainable development of the coal chemical industry and other high-carbon-emission industries in China; it not only saves the energy required for the production of products derived from solid waste recycling but also significantly reduces production and operational costs ; It simultaneously achieves low-cost and efficient capture and utilization of CO2 from coal chemical industry flue gases, finds the optimal solution to the equation \"X solid waste + Y carbon dioxide = negative-carbon building materials\", fills a gap in both international and domestic industries, and effectively sets a precedent in this field. The core technology employed in this project originates from the research team led by Professor Jiang Zhengwu at Tongji University. This team has been engaged for a long time in scientific research and technological development related to the use of solid waste for the production of negative-carbon green materials. Their independently developed CO2 mineralization technology uses bulk solid wastes with mineralization capabilities as primary raw materials; through the synergistic activation of various solid wastes, along with efficient transmission and in-depth mineralization of CO2, it is possible to significantly improve the performance of the resulting products as well as their carbon sequestration capacity. This technology enables the effective utilization of carbon dioxide from industrial exhaust gases at various concentrations ; The gelling components of the product are entirely made from industrial solid waste, and no external heat source is required in the production process. By developing such new types of negative-carbon building materials, it is possible to achieve the simultaneous treatment of large amounts of solid waste and CO2 emissions from industries such as chemicals, steel, metallurgy, and power generation. This approach helps to address the challenges related to the harmless disposal and resource utilization of such solid waste, as well as the difficulties in effectively capturing and utilizing CO2 from industrial emissions. Building on this research, the Functional Materials Research Institute has entered into in-depth cooperation with Professor Jiang Zhengwu’s team from Tongji University to carry out the commercialization and pilot-scale testing of the core technologies for solid waste mineralization. As a result, an industrial production process as well as the corresponding set of equipment for using pure solid waste to capture and mineralize carbon dioxide in order to produce negative-carbon building materials have been developed, thus creating a comprehensive solution for the entire process. At present, this solution enables the combined treatment of solid wastes with high mineralization activity (such as calcium carbide slag, steel slag, phosphorus slag, manganese slag, etc.) and those with low mineralization activity (such as fly ash, gasification slag, foundry sand, construction waste, etc.). It allows for the mineralization of CO2 from industrial flue gases under various conditions of temperature, pressure, and concentration, resulting in a range of high-value products such as wall materials, recycled aggregates, materials for municipal roads, and ecological slope protection structures. These products are widely used in sectors such as municipal engineering, construction, and water management, enabling the transformation of inexpensive waste into high-value goods. This approach truly achieves low-carbon emission throughout the entire life cycle of solid waste-based products, from the raw material stage to their application stage. Building on the successful trial operation of this project, the Institute of Functional Materials and Anhui Hongsi Fang New Building Materials Technology Co., Ltd. are also actively planning the renovation and construction of carbon dioxide pipelines, in order to make full preparations for the official commissioning of the project aimed at capturing and utilizing CO2 from large amounts of solid waste. Upon completion of the renovation, this project is expected to be able to handle nearly 1 million tons of various types of bulk solid waste each year. At the same time, it will capture and utilize at least 100,000 tons of CO2, which is equivalent to the carbon sequestration capacity of 100,000 mu of forest area per year, or the same as eliminating the emissions from nearly 60,000 economy cars for one year. Once it is put into formal operation, this project will serve as a model for low-carbon transformation in China’s coal chemical industry, and it will also mark a significant milestone on the path toward low-carbon, green, and circular development for this sector in our country At the same time, the Institute of Functional Materials will continue to work actively with various parties to promote low-carbon and sustainable development paths as well as comprehensive solutions for other high-carbon-emission industries such as the power sector, steel industry, and cement industry, thereby contributing to the early achievement of China’s \"dual carbon\" goals! Institute of Organic Functional Materials and Application Technologies: This institute is an innovative R&D institution established jointly by the Jiangsu Provincial Institute of Industrial Technology, the Suzhou Institute of Industrial Technology, the High-Speed Rail New City in Suzhou, and Professor Ren Tianbin’s team from Tongji University. Its goal is to leverage the innovative resources and models of these research institutions, Suzhou’s geographical advantages and industrial strengths, as well as Professor Ren Tianbin’s team’s expertise in transforming scientific achievements into commercial products, in order to create a hub for innovation in the field of functional materials that encompasses functions such as industrial technology research and development, transformation of scientific achievements, training of high-level talent, and support for innovative enterprises. The Environmental Protection Center of the Institute of Organic Functional Materials and Application Technologies focuses on the **dual-carbon strategy**. By addressing the needs related to carbon control and reduction in key sectors, it leverages resources from various platforms across government, industry, academia, research, and application fields. It brings together a team of scientists with extensive experience in technology research and development, as well as industry experts with practical experience in industrialization. Backed by over 20 key core technologies such as the thermal recovery of solid and wastewater, the mineralization of CO2, the engineering of high-performance films, and gel and nano-coating techniques, it provides comprehensive solutions for various application areas including coal chemical industry, steel manufacturing, power generation, functional films, and green agriculture. This approach aims to achieve simultaneous reductions in pollution and carbon emissions, and through innovation-driven efforts, to foster a low-carbon industrial ecosystem. Focusing on the development of the green environmental protection industry, as well as the transformation of environmental protection scientific and technological achievements and the incubation of related projects, the Functional Materials Research Center strives to identify the key elements and capabilities at various stages of turning environmental protection technologies into marketable products, thereby exploring the most effective approaches for integrating research, industry, education, and practical application in this field. Sino Salt Anhui Hongsi Fang Co., Ltd. is a wholly-owned subsidiary of China National Salt Industry Group Corporation. Headquartered in the Hefei Circular Economy Demonstration Park, it covers an area of over 5,000 mu and currently has 10 wholly-owned and holding subsidiaries, with more than 5,000 employees. The total assets amount to 15 billion yuan. To date, a series of industrial sectors such as coal chemical engineering, salt chemical engineering, fine chemical engineering, as well as new energy and new building materials have been developed, turning it into a comprehensive **large-scale chemical enterprise. The company has a **-level technology center, a provincial-level technology center, the Sinochem Salt Chemical Technology Center, and a post-doctoral research workstation. The company has won 9 provincial, ministerial, and municipal awards for scientific and technological progress. It has issued over 30 various technical standards (including 4 national standards, 2 industry standards, and 4 local standards), and holds 187 valid patents (of which 61 are invention patents). CSIC Anhui Hongsifang New Building Materials Technology Co., Ltd. is a subsidiary of CSIC Anhui Hongsifang Co., Ltd. Since its establishment, the company has been committed to green development and energy conservation & emission reduction. It focuses on the research, development, and innovation of new products while strictly managing product quality. As a result, its market share continues to expand. The company has invested hundreds of millions of yuan to establish multiple production lines for the resource utilization of solid waste. These lines can effectively process nearly one million tons of bulk industrial solid waste generated annually by Sinochem Salt Anhui Hongsifang Co., Ltd. and its subsidiaries, thus achieving comprehensive utilization by “turning waste into treasure”. In recent years, the company has actively responded to the **dual-carbon policy**, made arrangements in the field of low-carbon mineralization, and actively explored new pathways for low-carbon and green transformation and development. School of Materials Science and Engineering, Tongji University. Tongji University is a national key university directly under the Ministry of Education and jointly built with the Shanghai Municipal Government. It is a university included in the “Double First-Class” initiative, as well as a participant in the “Project 211” and “Project 985”. The School of Materials Science and Engineering at Tongji University is one of the earliest departments specializing in building materials established in China. Currently, its materials science program ranks within the top 1‰ globally according to the ESI international rankings, and it is among the top 100 programs in the world in terms of materials science as ranked by USNews. The research team on sustainable concrete led by Professor Jiang Zhengwu has been dedicated for a long time to areas such as the low-carbon and sustainable theories and application technologies related to cement concrete materials, the efficient recycling of large amounts of industrial solid waste, green high-performance concrete materials, the behavior of concrete materials in extreme environments, and cement-based intelligent self-healing materials. He has successively led and undertaken over fifty projects, including **key research and development initiatives**, 973 projects, **science and technology support programs**, National Natural Science Foundation projects, and major science and technology research projects in Shanghai. The achievements have won over 10 awards, including the **Second Prize for Technological Invention, the Second Prize for Technological Invention by the Ministry of Education, and the First Prize for Scientific and Technological Progress in Building Materials awarded by the Chinese Ceramic Society. He has published over 200 papers in domestic and international academic journals; more than 100 of these papers are indexed by SCI. His works have been cited over 4,000 times in total. He has also authored 6 academic books and been granted over 50 invention patents. The research results have been successfully applied in over 70 major projects, including the Beipanjiang Bridge – the world’s tallest bridge, the Three Gorges Dam, the Jinsha River Bridge, the Qingshuihe Bridge, the Hezhang Bridge, the Baling River Bridge, and the Donghai Bridge. Jiangsu Tongcuihe Technology Co., Ltd. is a technology company established as a joint venture between the Institute of Organic Functional Materials and Application Technologies and Henan Sanhe Group. Leveraging core technologies and the commercialization of scientific achievements, it possesses advanced capabilities in equipment manufacturing. The company primarily provides comprehensive technical solutions in the fields of solid waste resource utilization and low-carbon development.

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